I just posted a large excerpt from Ansible for DevOps over on the Server Check.in blog: Highly-Available Infrastructure Provisioning and Configuration with Ansible. In it, I describe a simple set of playbooks that configures a highly-available infrastructure primarily for PHP-based websites and web applications, using Varnish, Apache, Memcached, and MySQL, each configured in a way optimal for high-traffic and highly-available sites.

Here's a diagram of the ultimate infrastructure being built: